I'd forgotten all about Autoruns and I'm happy to see that it's still being updated! Thanks for the link sirgoit. 8-)
That really is quite a lot of time between the Windows loading animation and login prompt and the time between the desktop showing and being able to load Firefox and get to RPS is ridiculous. Try booting into Safe Mode by repeatedly pressing F8 right after the Acer logo goes away (after POST) and time the complete startup process again two more times to make sure there isn't some one-time difference. If your times are still very long, your hard drive is either too full and/or dying on you. If you get into Safe Mode pretty quickly, it means that the problem is Windows and/or startup programs.
Either way go to http://support.acer.com/product/defa...px?modelId=570 and download your User Manual (last green Download button), unzip the PDF and jump to page 21 (page 1 of the manual) to see how to open the Acer Empowering Technology program. Then jump to page 82 (page 62 of the manual) to see how to burn a restore DVD (in case your HDD is dying or dies at any time in the future) and how to restore your laptop to "factory default" (if your HDD is fine). A factory default restore typically formats your HDD and re-installs Windows to the exact state it was at when you first bought it, including any pre-installed bloatware apps. Because of the format process, you'll want to get all of your docs, videos, pics, etc. onto your external HDD before doing a factory default restore or before your drive dies on you.